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Research Papers

Oxygen Reduction Activity on a Nanosized Perovskite-Type Oxide Prepared by Polyvinyl Pyrrolidone Method

[+] Author and Article Information
Tsukasa Nagai

Research Institute for Ubiquitous Energy Devices,
National Institute of Advanced Industrial Science
and Technology (AIST),
1-8-31, Midorigaoka,
Ikeda, Osaka 563-8577, Japan
e-mail: tsukasa-nagai@aist.go.jp

Naoko Fujiwara

Research Institute for Ubiquitous Energy Devices,
National Institute of Advanced Industrial Science
and Technology (AIST),
1-8-31, Midorigaoka,
Ikeda, Osaka 563-8577, Japan
e-mail: n-fujiwara@aist.go.jp

Mitsunori Kitta

Research Institute for Ubiquitous Energy Devices,
National Institute of Advanced Industrial Science
and Technology (AIST),
1-8-31, Midorigaoka,
Ikeda, Osaka 563-8577, Japan
e-mail: m-kitta@aist.go.jp

Masafumi Asahi

Research Institute for Ubiquitous Energy Devices,
National Institute of Advanced Industrial Science
and Technology (AIST),
1-8-31, Midorigaoka,
Ikeda, Osaka 563-8577, Japan
e-mail: m.asahi@aist.go.jp

Shin-ichi Yamazaki

Research Institute for Ubiquitous Energy Devices,
National Institute of Advanced Industrial Science
and Technology (AIST),
1-8-31, Midorigaoka,
Ikeda, Osaka 563-8577, Japan
e-mail: s-yamazaki@aist.go.jp

Zyun Siroma

Research Institute for Ubiquitous Energy Devices,
National Institute of Advanced Industrial Science
and Technology (AIST),
1-8-31, Midorigaoka,
Ikeda, Osaka 563-8577, Japan
e-mail: siroma.z@aist.go.jp

Tsutomu Ioroi

Research Institute for Ubiquitous Energy Devices,
National Institute of Advanced Industrial Science
and Technology (AIST),
1-8-31, Midorigaoka,
Ikeda, Osaka 563-8577, Japan
e-mail: ioroi-t@aist.go.jp

1Corresponding author.

Contributed by the Advanced Energy Systems Division of ASME for publication in the JOURNAL OF FUEL CELL SCIENCE AND TECHNOLOGY. Manuscript received October 16, 2014; final manuscript received December 15, 2014; published online January 13, 2015. Assoc. Editor: Dr. Masashi Mori.

J. Fuel Cell Sci. Technol 12(2), 021007 (Apr 01, 2015) (5 pages) Paper No: FC-14-1123; doi: 10.1115/1.4029424 History: Received October 16, 2014; Revised December 15, 2014; Online January 13, 2015

A nanosized perovskite-type oxide supported on carbon black (perovskite/C) was prepared by the polyvinyl pyrrolidone (PVP) addition method and subsequent mechanical milling with carbon black. Transmission electron microscope (TEM) observation and scanning transmission electron microscope (STEM)–energy dispersive X-ray (EDX) mapping clearly revealed that the oxide prepared by the PVP method was small (ca. 20 nm) and highly dispersed on the carbon support. The oxygen reduction reaction (ORR) activity on the perovskite/C catalyst was investigated with rotating ring-disk electrode (RRDE) measurement in an alkaline solution at 25 °C. The prepared perovskite/C catalyst showed enhanced activity compared to catalysts obtained by the conventional solid state reaction and citrate process; i.e., a positive shift of the onset potential and increased ORR current at a disk electrode. The present catalyst was also associated with decreased ring current.

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References

Savy, M., 1968, “Oxygen Reduction in Alkaline Solution on Semiconducting Cobalt Oxide Electrodes,” Electrochim. Acta, 3(6), pp. 1359–1376. [CrossRef]
Gasteiger, H. A., Kocha, S. S., Sompalli, B., and Wagner, F. T., 2005, “Activity Benchmarks and Requirements for Pt, Pt-Alloy, and Non-Pt Oxygen Reduction Catalysts for PEMFCs,” Appl. Catal., B, 56(1–2), pp. 9–35. [CrossRef]
Spendelow, J. S., and Wieckwski, A., 2007, “Electrocatalysis of Oxygen Reduction and Small Alcohol Oxidation in Alkaline Media,” Phys. Chem. Chem. Phys., 9(21), pp. 2654–2675. [CrossRef] [PubMed]
Asazawa, K., Yamada, K., Tanaka, H., Oka, A., Taniguchi, M., and Kobayashi, T., 2007, “A Platinum-Free Zero-Carbon-Emission Easy Fuelling Direct Hydrazine Fuel Cell for Vehicles,” Angew. Chem., Int. Ed., 46(42), pp. 8024–8027. [CrossRef]
Slanac, D. A., Lie, A., Paulson, J. A., Stevenson, K. J., and Johnston, K. P., 2012, “Bifunctional Catalysts for Alkaline Oxygen Reduction Reaction Via Promotion of Ligand and Ensemble Effects at Ag/MnOx Nanodomains,” J. Phys. Chem. C, 116(20), pp. 11032–11039. [CrossRef]
Meadowcroft, D. B., 1970, “Low-Cost Oxygen Electrode Material,” Nature, 226(5248), pp. 847–848. [CrossRef] [PubMed]
Shimizu, Y., Uemura, K., Matsuda, H., Miura, N., and Yamazoe, N., 1990,”Bi-Functional Oxygen Electrode Using Large Surface Area La1−xCaxCoO3 for Rechargeable Metal–Air Battery,” J. Electrochem. Soc., 137(11), pp. 3430–3433. [CrossRef]
Suntivich, J., Gasteiger, H. A., Yabuuchi, N., Nakanishi, H., Goodenough, J. B., and Shao-Horn, Y., 2011, “Design Principles for Oxygen-Reduction Activity on Perovskite Oxide Catalysts for Fuel Cells and Metal–Air Batteries,” Nat. Chem., 3(8), pp. 546–550. [CrossRef] [PubMed]
Kinoshita, K., 1988, Carbon-Electrochemical and Physicochemical Properties, Wiley, New York.
Song, C., and Zhang, J., 2008, “Electrocatalytic Oxygen Reduction Reaction,” PEM Fuel Cell Electrocatalysts and Catalyst Layers: Fundamentals and Applications, Springer, London, pp. 89–134.
Poux, T., Napolskiy, F. S., Dintzer, T., Kerangueven, G., Istomin, S. Y., Tsirlina, G. A., Antipov, E. V., and Savinova, E. R., 2012, “Dual Role of Carbon in the Catalytic Layers of Perovskite/Carbon Composites for the Electrocatalytic Oxygen Reduction Reaction,” Catal. Today, 189(1), pp. 83–92. [CrossRef]
Bursell, M., Pirjamali, M., and Kiros, Y., 2002, “La0.6Ca0.4CoO3, La0.1Ca0.9MnO3, and LaNiO3 as Bifunctional Oxygen Electrodes,” Electrochim. Acta, 47(10), pp. 1651–1660. [CrossRef]
Thiele, D., and Zuttel, A., 2008, “Electrochemical Characterization of Air Electrodes Based on La0.6Sr0.4CoO3 and Carbon Nanotubes,” J. Power Sources, 183(2), pp. 590–594. [CrossRef]
Hayashi, M., Uemura, H., Shimanoe, K., Miura, N., and Yamazoe, N., 1998, “Enhanced Electrocatalytic Activity for Oxygen Reduction Over Carbon-Supported LaMnO3 Prepared by Reverse Micelle Method,” Electrochem. Solid-State Lett., 1(6), pp. 268–270. [CrossRef]
Haider, M. A., Capizzi, A. J., Murayama, M., and McIntosh, S., 2011, “Reverse Micelle Synthesis of Perovskite Oxide Nanoparticles,” Solid State Ionics, 196(1), pp. 65–72. [CrossRef]
Tulloch, J., and Donne, S. W., 2009, “Activity of Perovskite La1−xSrxMnO3 Catalysts Towards Oxygen Reduction in Alkaline Electrolytes,” J. Power Sources, 188(2), pp. 359–366. [CrossRef]
Yuasa, M., Yamazoe, N., and Shimanoe, K., 2011, “Durability of Carbon-Supported La-Mn-Based Perovskite-Type Oxides as Oxygen Reduction Catalysts in Strong Alkaline Solution,” J. Electrochem. Soc., 158(4), pp. A411–A416. [CrossRef]
Nagai, T., Fujiwara, N., Asahi, M., Yamazaki, S., Siroma, Z., and Ioroi, T., 2014, “Synthesis of Nano-Sized Perovskite-Type Oxide With the Use of Polyvinyl Pyrrolidone,” J. Asian Ceram. Soc., 2(4), pp. 329–332. [CrossRef]
Fujiwara, N., Siroma, Z., Yamazaki, S., Asahi, M., Nagai, T., and Ioroi, T., 2013, “Reversible Air Electrodes Using Perovskite Oxide Catalysts Complexed With Carbon Black,” 80th Meeting of the Electrochemical Society of Japan, Katahira, Japan, Mar. 29–31, p. 3A21.
Paulus, U. A., Schmidt, T. J., Gasteiger, H. A., and Behm, R. J., 2001, “Oxygen Reduction on a High-Surface Area Pt/Vulcan Carbon Catalyst: A Thin-Film Rotating Ring-Disk Electrode Study,” J. Electroanal. Chem., 495(2), pp. 134–145. [CrossRef]

Figures

Grahic Jump Location
Fig. 1

XRD patterns for carbon-supported La0.6Sr0.4Mn0.6Fe0.4O3 (La0.6Sr0.4Mn0.6Fe0.4O3/C) prepared by different processes (•: perovskite-type structure). Corresponding data for carbon are also shown for comparison.

Grahic Jump Location
Fig. 2

TEM image of the La0.6Sr0.4Mn0.6Fe0.4O3/C catalysts (PVP method (a), citrate process (b), and solid state reaction (c)). Dark spots indicate the presence of La0.6Sr0.4Mn0.6Fe0.4O3 particles.

Grahic Jump Location
Fig. 3

STEM–EDX elemental mapping images of the La0.6Sr0.4Mn0.6Fe0.4O3/C catalysts (PVP method (a), citrate process (b), and solid state reaction (c)). The scale bar in HAADF applies to all images.

Grahic Jump Location
Fig. 4

(a) Hydrodynamic voltammograms in O2-saturated 0.1 M KOH solution obtained at 10 mV s−1, 900 rpm, and 25 °C for La0.6Sr0.4Mn0.6Fe0.4O3/C. (b) Ring electrode current during oxygen reduction. (PVP addition (1), citrate process (2), and solid state reaction (3)), La0.6Sr0.4Mn0.6Fe0.4O3 as prepared by the PVP method (4), carbon (5), and La0.6Sr0.4Mn0.6Fe0.4O3(PVP) + C before ball milling (6). Corresponding data for commercially available Pt/C are also shown as (7).

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